Structure and properties of an eight-coordinate Mn(II) complex that demonstrates a high water relaxivity.
نویسندگان
چکیده
An air-stable eight-coordinate (8C) Mn(II)N(8) complex has been synthesized utilizing an N(4) imidazole/imine ligand. The 8C dodecahedral geometry is structurally robust as the Mn complex is stable to air, NO(g), and potential coordinating anions. The structural, spectroscopic and water relaxivity properties of this complex are reported.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 29 شماره
صفحات -
تاریخ انتشار 2011